MCQs on Auto Oxidation and Disproportionation

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MCQs on Auto Oxidation and Disproportionation

1. Which one of the following will not reduce an acidified solution of potassium dichromate (VI)?
(a) (CH3)2C(OH)CH3
(b) FeSO4
(c) CH3CH2CH(OH)CH3
(d) Zn

Answer

Answer: (a)


2. 25.4g of iodine and 14.2g of chlorine is made to react completely to yield a mixture of ICl and ICl3. Calculate the ratio of moles of ICl and ICl3
(a) 1:1
(b) 1:2
(c) 1:3
(d) 2:3

Answer

Answer: (a)


3. Which of the following has been arranged in order of decreasing average oxidation number of sulphur?
(a) H2S2O7 > Na2S4O6 > Na2S2O3 > S8
(b) SO2+ > SO42- > SO32- > HSO4
(c) H2SO5 > H2SO3 > SCl2 > H2S
(d) H2SO4 > SO2 > H2S > H2S2O8

Answer

Answer: (c)


4. The decomposition of KClO3 to KCl and O2 on heating is an example of
(a) intermolecular redox change
(b) intramolecular redox change
(c) disproportionation or auto redox change
(d) none of these

Answer

Answer: (b)


5. Disproportionation means
(a) only oxidation
(b) only reduction
(c) both, oxidation and reduction of a reactant
(d) neither oxidation nor reduction

Answer

Answer: (c)


6. The compounds behaving both oxidizing, as well as a reducing agent, is
(a) H2O2
(b) SO2
(c) HNO2
(d) HNO3

Answer

Answer: (a,b,c)


7. A substance which can be oxidised as well as reduced easily is
(a) HCl
(b) HClO
(c) HClO3
(d) HClO4

Answer

Answer: (b,c)


8. Equivalent mass of oxidising agent in the reaction

SO2 + 2H2S → 3S + 2H2O
(a) 32
(b) 64
(c) 16
(d) 8

Answer

Answer: (c)


9. The oxidation number of iron in Fe3O4 is
(a) +2
(b) +3
(c) 8/3
(d) ⅔

Answer

Answer: (a,b)


10. Oxidation numbers of chlorine in Cl2O, Cl2 and ClO3 are respectively
(a) +1, -1, +5
(b) +1, 0, -1
(c) -1, 0, +1
(d) +1, 0, +5

Answer

Answer: (d)


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